Captain Caveman and the Teen Angels

The 1977 and 1978 episodes were originally broadcasted as segments on the package show Scooby's All-Star Laff-A-Lympics and Scooby's All-Stars. The 1980 episodes featured Captain Caveman and the Teen Angels in their own half-hour timeslot.

• Mel BlancCaptain Caveman (voice)
• Vernee WatsonDee Dee Skyes (voice)
• Marilyn SchrefflerBrenda Chance (voice)
• Laurel PageTaffy Dare (voice)
• Nicole JaffeAdditional Voices (voice)
• Michael StullAdditional Voices (voice)
• Heather North(voices)
• Casey Kasem(voice)
• Frank Welker(voices)